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System Size Dependence of a Product of Intensive Phase Variables

     In this appendix, we show that the phase average of a product of intensive phase variables is of order , with N being the number of particles in the system.

Let us begin by noting that the phase variable can be written as an average over individual particles:

Then we find that

 

In a system where the order is short range (for example a fluid far from its critical point), we would expect that correlations of the form only picks up contributions from its nearest neighbours, and is consequently intensive. More generally, we can say that is intensive. The first term on the right hand side of (gif) is clearly intensive, so we find



Russell Standish
Thu May 18 11:43:52 EST 1995